TY - JOUR
T1 - μ‐Hydroxobis(μ‐formato)hexaaquadichromium(III), an Intermediate in the Formation of Basic Chromium Carboxylates
AU - Turowski, Petra N.
AU - Bino, Avi
AU - Lippard, Stephen J.
PY - 1990/7
Y1 - 1990/7
N2 - For over 100 years it has been known that, during the synthesis of basic, dark green chromium carboxylates, violet compounds are also formed. The first such species has now been characterized. The complex cation 1 was obtained upon reduction of chromium(VI) oxide with formic acid and isolated as its p‐toluenesulfonate. Complex 1 is the first Cr 2III complex containing one μ‐hydroxo and two μ‐carboxylato ligands. (Formula Presented.) (Figure Presented.)
AB - For over 100 years it has been known that, during the synthesis of basic, dark green chromium carboxylates, violet compounds are also formed. The first such species has now been characterized. The complex cation 1 was obtained upon reduction of chromium(VI) oxide with formic acid and isolated as its p‐toluenesulfonate. Complex 1 is the first Cr 2III complex containing one μ‐hydroxo and two μ‐carboxylato ligands. (Formula Presented.) (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748242000&partnerID=8YFLogxK
U2 - 10.1002/anie.199008111
DO - 10.1002/anie.199008111
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:33748242000
SN - 0570-0833
VL - 29
SP - 811
EP - 812
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 7
ER -