3D printing by stereolithography using thermal initiators

Doron Kam, Omri Rulf, Amir Reisinger, Rama Lieberman, Shlomo Magdassi

Research output: Contribution to journalArticlepeer-review

Abstract

Additive manufacturing technologies based on stereolithography rely on initiating spatial photopolymerization by using photoinitiators activated by UV-visible light. Many applications requiring printing in water are limited since water-soluble photoinitiators are scarce, and their price is skyrocketing. On the contrary, thermal initiators are widely used in the chemical industry for polymerization processes due to their low cost and simplicity of initiation by heat at low temperatures. However, such initiators were never used in 3D printing technologies, such as vat photopolymerization stereolithography, since localizing the heat at specific printing voxels is impossible. Here we propose using a thermal initiator for 3D printing for localized polymerization processes by near-infrared and visible light irradiation without conventional photoinitiators. This is enabled by using gold nanorods or silver nanoparticles at very low concentrations as photothermal converters in aqueous and non-aqueous mediums. Our proof of concept demonstrates the fabrication of hydrogel and polymeric objects using stereolithography-based 3D printers, vat photopolymerization, and two-photon printing.

Original languageAmerican English
Pages (from-to)2285
Number of pages1
JournalNature Communications
Volume15
Issue number1
DOIs
StatePublished - 13 Mar 2024

Bibliographical note

Publisher Copyright:
© 2024. The Author(s).

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