4f yields 4f TRANSITIONS AND CHARGE TRANSFER SPECTRA OF Eu3 + , 4f yields 5d SPECTRA OF Tb3 + , AND 1S0 yields 3P1 SPECTRA OF Pb2 + IN ALKALINE EARTH METAPHOSPHATE GLASSES.

R. Reisfeld*, L. Boehm, M. Ish-Shalom, R. Fischer

*Corresponding author for this work

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15 Scopus citations

Abstract

Oscillator strengths and quantum efficiencies of Eu**3** plus in MO-P//2O//5 glasses were measured (M equals Mg, Ca, Sr, or Ba). The ratios of fluorescence from **5D//1 and **5D//0 levels of Eu**3** plus to the **7F multiplet is explained by interaction with the vibrational modes of the various glasses. From the fact that charge transfer spectra of Eu**3** plus , 4f yields 5d spectra of Tb**3** plus , and **1S//0 yields **3P//1 of Pb**2** plus did not show any difference in the wave number of maximum absorption when the network modifier was interchanged, it was concluded that the symmetrical part of the crystal field of the glass is independent of the network modifier. A standard for fluorescence quantum efficiency is proposed.

Original languageEnglish
Pages (from-to)76-80
Number of pages5
JournalPhysics and Chemistry of Glasses
Volume15
Issue number3
StatePublished - 1974

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