A Conversation on New Types of Chemical Bonds

Philippe C. Hiberty; D. Danovich; Sason Shaik

doi:10.1002/ijch.202000114

A Conversation on New Types of Chemical Bonds

Philippe C. Hiberty^*
, D. Danovich
, Sason Shaik^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Review article › peer-review

9 Scopus citations

Abstract

This conversation tells a panoramic story on bonding motifs discovered and/pre-conceptualized by VB theory (VBT). Initially, the essay recounts how the authors discovered charge-shift bonding (CSB) which enriched the landscape of electron-pair bonding. This is followed by triplet-pair bonds (TPB), between pairs of electrons that possess identical spins. And finally, a story is told of new adventures in describing excited states and their bonding. This is also a tale of a wonderful and insightful theory, Valence Bond Theory, which is coming of age. This is all recounted as a conversation between three scientists who participated in this research, and are conversing here in a Socratic-Talmudic trialogue.

Original language	English
Article number	e202000114
Journal	Israel Journal of Chemistry
Volume	62
Issue number	1-2
DOIs	https://doi.org/10.1002/ijch.202000114
State	Published - Feb 2022

Bibliographical note

Publisher Copyright:
© 2021 Wiley-VCH GmbH

Keywords

Bonding in high-spin metal clusters
Charge-shift bonding
Valence-bond Theory
excited states

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10.1002/ijch.202000114

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title = "A Conversation on New Types of Chemical Bonds",

abstract = "This conversation tells a panoramic story on bonding motifs discovered and/pre-conceptualized by VB theory (VBT). Initially, the essay recounts how the authors discovered charge-shift bonding (CSB) which enriched the landscape of electron-pair bonding. This is followed by triplet-pair bonds (TPB), between pairs of electrons that possess identical spins. And finally, a story is told of new adventures in describing excited states and their bonding. This is also a tale of a wonderful and insightful theory, Valence Bond Theory, which is coming of age. This is all recounted as a conversation between three scientists who participated in this research, and are conversing here in a Socratic-Talmudic trialogue.",

keywords = "Bonding in high-spin metal clusters, Charge-shift bonding, Valence-bond Theory, excited states",

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N2 - This conversation tells a panoramic story on bonding motifs discovered and/pre-conceptualized by VB theory (VBT). Initially, the essay recounts how the authors discovered charge-shift bonding (CSB) which enriched the landscape of electron-pair bonding. This is followed by triplet-pair bonds (TPB), between pairs of electrons that possess identical spins. And finally, a story is told of new adventures in describing excited states and their bonding. This is also a tale of a wonderful and insightful theory, Valence Bond Theory, which is coming of age. This is all recounted as a conversation between three scientists who participated in this research, and are conversing here in a Socratic-Talmudic trialogue.

AB - This conversation tells a panoramic story on bonding motifs discovered and/pre-conceptualized by VB theory (VBT). Initially, the essay recounts how the authors discovered charge-shift bonding (CSB) which enriched the landscape of electron-pair bonding. This is followed by triplet-pair bonds (TPB), between pairs of electrons that possess identical spins. And finally, a story is told of new adventures in describing excited states and their bonding. This is also a tale of a wonderful and insightful theory, Valence Bond Theory, which is coming of age. This is all recounted as a conversation between three scientists who participated in this research, and are conversing here in a Socratic-Talmudic trialogue.

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KW - Valence-bond Theory

KW - excited states

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A Conversation on New Types of Chemical Bonds

Abstract

Bibliographical note

Keywords

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