A direct measurement of intramolecular hydrophobic interactions

A. Ben-Naim*, J. Wilf

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

A theoretical argument is used to suggest a new method of processing experimental results to obtain information on pairwise hydrophobic interactions. The experimental data consist of measurements of solubilities and partition coefficients of some alkylbenzene molecules in water and in n-hexane. From these data one may extract information on the intramolecular hydrophobic interactions, i.e., interaction between two alkyl groups attached to a "backbone" molecule. Some preliminary results are reported and interpreted.

Original languageEnglish
Pages (from-to)771-777
Number of pages7
JournalThe Journal of Chemical Physics
Volume70
Issue number2
DOIs
StatePublished - 1979

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