TY - JOUR
T1 - A heterocyclic arene oxide. 5,6‐Diphenylbenz[c]acridine 5,6‐oxide
AU - Avnir, David
AU - Blum, Jochanan
PY - 1976/6
Y1 - 1976/6
N2 - The first synthesis of a benz[c]acridine 5,6‐oxide is described. Treatment of 5,6‐benz[c]‐acridinequinone with phenylmagnesium bromide results in the formation of a trans‐diol, which gives the title compound upon dehydration with dimethylformamide dimethylacetal. In sulfuric acid, the epoxide rearranges mainly into 6,6‐diphenyl‐5‐benz[c]acridone.
AB - The first synthesis of a benz[c]acridine 5,6‐oxide is described. Treatment of 5,6‐benz[c]‐acridinequinone with phenylmagnesium bromide results in the formation of a trans‐diol, which gives the title compound upon dehydration with dimethylformamide dimethylacetal. In sulfuric acid, the epoxide rearranges mainly into 6,6‐diphenyl‐5‐benz[c]acridone.
UR - http://www.scopus.com/inward/record.url?scp=84980294987&partnerID=8YFLogxK
U2 - 10.1002/jhet.5570130342
DO - 10.1002/jhet.5570130342
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AN - SCOPUS:84980294987
SN - 0022-152X
VL - 13
SP - 619
EP - 621
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
IS - 3
ER -