A Reference Electrode for Organic Solvents Based on Modified Polyethylenimine Loaded with Fe(cn)3 6 -/4-

Ana Kaminsky; Ltamar Willner; Daniel Mandler

doi:10.1149/1.2056178

A Reference Electrode for Organic Solvents Based on Modified Polyethylenimine Loaded with Fe(cn)³ ₆ ^-/4-

Ana Kaminsky, Ltamar Willner, Daniel Mandler

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A cross-linked polymer composed of polyethylenimine reacted with 1,4-dibromobutane coated on a glassy carbon electrode and containing negatively charged ions, Fe(CN)36^/4“, is proposed as a reference electrode in organic solvents. The system exhibits a relatively stable potential (±10 mV) over a period of several days in acetonitrile and a reasonable potential stability for several hours in N, N’-dimethyl-formamide and dichloromethane. The different parameters that affect the behavior of the GCE/PEI/Fe(CN)³ ₆ ^/4“ are characterized.

Original language	English
Journal	Journal of the Electrochemical Society
Volume	140
Issue number	3
DOIs	https://doi.org/10.1149/1.2056178
State	Published - 1993

Keywords

electrochemical analysis
electrochemical electrodes
organic compounds
oxidation
polymer electrolytes

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10.1149/1.2056178

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abstract = "A cross-linked polymer composed of polyethylenimine reacted with 1,4-dibromobutane coated on a glassy carbon electrode and containing negatively charged ions, Fe(CN)36/4“, is proposed as a reference electrode in organic solvents. The system exhibits a relatively stable potential (±10 mV) over a period of several days in acetonitrile and a reasonable potential stability for several hours in N, N{\textquoteright}-dimethyl-formamide and dichloromethane. The different parameters that affect the behavior of the GCE/PEI/Fe(CN)3 6 /4“ are characterized.",

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AU - Willner, Ltamar

AU - Mandler, Daniel

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Y1 - 1993

N2 - A cross-linked polymer composed of polyethylenimine reacted with 1,4-dibromobutane coated on a glassy carbon electrode and containing negatively charged ions, Fe(CN)36/4“, is proposed as a reference electrode in organic solvents. The system exhibits a relatively stable potential (±10 mV) over a period of several days in acetonitrile and a reasonable potential stability for several hours in N, N’-dimethyl-formamide and dichloromethane. The different parameters that affect the behavior of the GCE/PEI/Fe(CN)3 6 /4“ are characterized.

AB - A cross-linked polymer composed of polyethylenimine reacted with 1,4-dibromobutane coated on a glassy carbon electrode and containing negatively charged ions, Fe(CN)36/4“, is proposed as a reference electrode in organic solvents. The system exhibits a relatively stable potential (±10 mV) over a period of several days in acetonitrile and a reasonable potential stability for several hours in N, N’-dimethyl-formamide and dichloromethane. The different parameters that affect the behavior of the GCE/PEI/Fe(CN)3 6 /4“ are characterized.

KW - electrochemical analysis

KW - electrochemical electrodes

KW - organic compounds

KW - oxidation

KW - polymer electrolytes

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A Reference Electrode for Organic Solvents Based on Modified Polyethylenimine Loaded with Fe(cn)³ ₆ ^-/4-

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Keywords

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