TY - JOUR
T1 - A spectrophotometric investigation of the reaction between diethylaluminum halides and titanium tetrachloride in carbon tetrachloride
AU - Behar, David
AU - Feilchenfeld, Hans
PY - 1965/10
Y1 - 1965/10
N2 - The reactions between diethylaluminum halides and titanium tetrachloride in carbon tetrachloride have been studied by UV absorption spectrophotometry. No titanium trichloride precipitates, though titanium tetrachloride disappears. Apparently ligand exchange takes place and ethyltitanium trichloride is formed. When excess of diethylaluminum bromide is present, a complex is formed. On standing, the ethyltitanium trichloride is eventually converted back into titanium tetrachloride.
AB - The reactions between diethylaluminum halides and titanium tetrachloride in carbon tetrachloride have been studied by UV absorption spectrophotometry. No titanium trichloride precipitates, though titanium tetrachloride disappears. Apparently ligand exchange takes place and ethyltitanium trichloride is formed. When excess of diethylaluminum bromide is present, a complex is formed. On standing, the ethyltitanium trichloride is eventually converted back into titanium tetrachloride.
UR - http://www.scopus.com/inward/record.url?scp=50549210800&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)88833-6
DO - 10.1016/S0022-328X(00)88833-6
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AN - SCOPUS:50549210800
SN - 0022-328X
VL - 4
SP - 278
EP - 283
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 4
ER -