Achiral Hexaisopropylbenzene Isotopomers: Analogues of the Achiral Trihydroxyglutaric Acid Diastereomers

Silvio E. Biali; Kurt Mislow; Alberto Gutiérrez

doi:10.1021/jo00241a038

Achiral Hexaisopropylbenzene Isotopomers: Analogues of the Achiral Trihydroxyglutaric Acid Diastereomers

Silvio E. Biali
, Kurt Mislow
, Alberto Gutiérrez

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Certain derivatives of hexaisopropylbenzene (hib) may exist as achiral diastereomers which are distinguished by the sense of directionality of the isopropyl C-H methine vectors and which, though devoid of conventional stereocenters, are conceptually related to the achiral 2,3,4-trihydroxyglutaric acid diastereomers.¹ We now report the first synthesis of such stereoisomers.

Original language	English
Pages (from-to)	1316-1318
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	53
Issue number	6
DOIs	https://doi.org/10.1021/jo00241a038
State	Published - 1 Mar 1988
Externally published	Yes

Access to Document

10.1021/jo00241a038

Cite this

@article{8dbddd29f6c640d99fadf9c6b87e5a38,

title = "Achiral Hexaisopropylbenzene Isotopomers: Analogues of the Achiral Trihydroxyglutaric Acid Diastereomers",

abstract = "Certain derivatives of hexaisopropylbenzene (hib) may exist as achiral diastereomers which are distinguished by the sense of directionality of the isopropyl C-H methine vectors and which, though devoid of conventional stereocenters, are conceptually related to the achiral 2,3,4-trihydroxyglutaric acid diastereomers.1 We now report the first synthesis of such stereoisomers.",

author = "Biali, \{Silvio E.\} and Kurt Mislow and Alberto Guti{\'e}rrez",

year = "1988",

month = mar,

day = "1",

doi = "10.1021/jo00241a038",

language = "אנגלית",

volume = "53",

pages = "1316--1318",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Achiral Hexaisopropylbenzene Isotopomers

T2 - Analogues of the Achiral Trihydroxyglutaric Acid Diastereomers

AU - Biali, Silvio E.

AU - Mislow, Kurt

AU - Gutiérrez, Alberto

PY - 1988/3/1

Y1 - 1988/3/1

N2 - Certain derivatives of hexaisopropylbenzene (hib) may exist as achiral diastereomers which are distinguished by the sense of directionality of the isopropyl C-H methine vectors and which, though devoid of conventional stereocenters, are conceptually related to the achiral 2,3,4-trihydroxyglutaric acid diastereomers.1 We now report the first synthesis of such stereoisomers.

AB - Certain derivatives of hexaisopropylbenzene (hib) may exist as achiral diastereomers which are distinguished by the sense of directionality of the isopropyl C-H methine vectors and which, though devoid of conventional stereocenters, are conceptually related to the achiral 2,3,4-trihydroxyglutaric acid diastereomers.1 We now report the first synthesis of such stereoisomers.

UR - https://www.scopus.com/pages/publications/0000289405

U2 - 10.1021/jo00241a038

DO - 10.1021/jo00241a038

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0000289405

SN - 0022-3263

VL - 53

SP - 1316

EP - 1318

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 6

ER -

Achiral Hexaisopropylbenzene Isotopomers: Analogues of the Achiral Trihydroxyglutaric Acid Diastereomers

Abstract

Access to Document

Other files and links

Fingerprint

Cite this