Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2MO10O40]5- polyoxometalate ion

Revital Ben-Daniel; Ronny Neumann

doi:10.1002/anie.200390062

Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV₂MO₁₀O₄₀]^5- polyoxometalate ion

Revital Ben-Daniel
, Ronny Neumann^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

A vanadium-substituted polyoxomolybdate ion ([PV₂Mo₁₀O₄₀]^5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

Original language	English
Pages (from-to)	92-95
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	1
DOIs	https://doi.org/10.1002/anie.200390062
State	Published - 3 Jan 2003
Externally published	Yes

Keywords

Alcohols
Homogeneous catalysis
Nitrogen oxides
Oxidation
Polyoxometalates

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10.1002/anie.200390062

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abstract = "A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).",

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AU - Neumann, Ronny

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N2 - A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

AB - A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

KW - Alcohols

KW - Homogeneous catalysis

KW - Nitrogen oxides

KW - Oxidation

KW - Polyoxometalates

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IS - 1

ER -

Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV₂MO₁₀O₄₀]^5- polyoxometalate ion

Abstract

Keywords

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