TY - JOUR
T1 - Adapting approximate-memory potentials for time-dependent density functional theory
AU - Kurzweil, Yair
AU - Baer, Roi
PY - 2008/2/27
Y1 - 2008/2/27
N2 - Frequency dependent exchange-correlation kernels for time-dependent density functional theory can be used to construct approximate exchange-correlation potentials. The resulting potentials are usually not translationally covariant nor do they obey the so-called zero-force condition. These two basic symmetry requirements are essential for using the potentials in actual applications (even in the linear regime). We provide two pragmatic methods for fully imposing these conditions for both linear and nonlinear regimes. As an example, we take the Gross and Kohn frequency dependent XC functional, correct it, and numerically test it on a sodium metal cluster. Violation of the basic symmetries causes instabilities or spurious low frequency modes.
AB - Frequency dependent exchange-correlation kernels for time-dependent density functional theory can be used to construct approximate exchange-correlation potentials. The resulting potentials are usually not translationally covariant nor do they obey the so-called zero-force condition. These two basic symmetry requirements are essential for using the potentials in actual applications (even in the linear regime). We provide two pragmatic methods for fully imposing these conditions for both linear and nonlinear regimes. As an example, we take the Gross and Kohn frequency dependent XC functional, correct it, and numerically test it on a sodium metal cluster. Violation of the basic symmetries causes instabilities or spurious low frequency modes.
UR - http://www.scopus.com/inward/record.url?scp=40849118178&partnerID=8YFLogxK
U2 - 10.1103/PhysRevB.77.085121
DO - 10.1103/PhysRevB.77.085121
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AN - SCOPUS:40849118178
SN - 1098-0121
VL - 77
JO - Physical Review B - Condensed Matter and Materials Physics
JF - Physical Review B - Condensed Matter and Materials Physics
IS - 8
M1 - 085121
ER -