Additions and Corrections: The Mechanism of the Dismutation of Superoxide Catalyzed by Copper(II) Phenanthroline Complex and of the Oxidation of Copper(I) Phenanthroline Complex by Oxygen in Aqueous Solution. (Journal of the American Chemical Society (1984) 106(9) (2739–2739) (10.1021/ja00363a012))

Sara Goldstein, Gidon Czapski

Research output: Contribution to journalComment/debate

Abstract

E°O2/O2- = -0.33 V which was used is defined for 1 at of O2. In our calculations the value should be E°O2/O2- = -0.16 V which is defined for 1 M of O2. On page 7279 in the paragraph Redox Potential of (op)2Cu2+ the following corrections should be made: E°0l/of should be -0.16 V rather than -0.33 V; K,°(0p)2cu2+/(op)2Cu+ should be 0.11 V rather than -0.055 V; Kl2 should be 1.66 X 1013 rather than 5.62 X 1015; and Al12 should be 1.77 X 10-5 M-1 s-1 rather than 5.25 X 10-8 M1 s. On page 7280, 9th line in Conclusion: E°(0p)2cu2+/(oP)2Cu+ should be 0.11 V rather than -0.055 V.

Original languageEnglish
Pages (from-to)2739
Number of pages1
JournalJournal of the American Chemical Society
Volume106
Issue number9
DOIs
StatePublished - 1 May 1984

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