Abstract
We construct the exact exchange-correlation potential of time-dependent density-functional theory and the approximation to it that is adiabatic but exact otherwise. For the strong-field double ionization of the Helium atom these two potentials are virtually identical. Thus, memory effects play a negligible role in this paradigm process of nonlinear, nonperturbative electron dynamics. We identify the regime of high-frequency excitations where the adiabatic approximation breaks down and explicitly calculate the nonadiabatic contribution to the exchange-correlation potential.
Original language | English |
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Article number | 153004 |
Journal | Physical Review Letters |
Volume | 100 |
Issue number | 15 |
DOIs | |
State | Published - 18 Apr 2008 |
Externally published | Yes |