Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Ronny Neumann; Alexander M. Khenkin

doi:10.1039/a804396e

Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Ronny Neumann^*, Alexander M. Khenkin

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

Manganese substituted polyoxometalates (POMs), such as Li₁₂[Mn^II₂ZnW(ZnW₉O ₃₄)₂] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

Original language	English
Pages (from-to)	1967-1968
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a804396e
State	Published - 21 Sep 1998

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title = "Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species",

abstract = "Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.",

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AU - Neumann, Ronny

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N2 - Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

AB - Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O 34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV-VIS and ESR at -78 °C was postulated to be a reactive manganese ozonide species.

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Alkane oxidation with manganese substituted polyoxometalates in aqueous media with ozone and the intermediacy of manganese ozonide species

Abstract

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