Americium(III) Perxenate

Y. Marcus; Donald Cohen

doi:10.1021/ic50044a022

Americium(III) Perxenate

Y. Marcus
, Donald Cohen

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Americium perxenate has been prepared by precipitation from basic solutions of americium(III). The compound is orange and shows the characteristic absorption bands of Am(III) in the visible and near-infrared regions, as well as the characteristic infrared absorption at 650-680 cm⁻¹ for the Xe-O vibration in perxenate. The compound is highly hydrated and has the stoichiometric composition Am₄(XeO₆)₃40H₂O. Its solubility in water is 4.6 X 10⁻⁵ M. The compound dissolves in acid to form Am(VI) and Am(V).

Original language	English
Pages (from-to)	1740-1743
Number of pages	4
Journal	Inorganic Chemistry
Volume	5
Issue number	10
DOIs	https://doi.org/10.1021/ic50044a022
State	Published - Oct 1966
Externally published	Yes

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title = "Americium(III) Perxenate",

abstract = "Americium perxenate has been prepared by precipitation from basic solutions of americium(III). The compound is orange and shows the characteristic absorption bands of Am(III) in the visible and near-infrared regions, as well as the characteristic infrared absorption at 650-680 cm−1 for the Xe-O vibration in perxenate. The compound is highly hydrated and has the stoichiometric composition Am4(XeO6)340H2O. Its solubility in water is 4.6 X 10−5 M. The compound dissolves in acid to form Am(VI) and Am(V).",

author = "Y. Marcus and Donald Cohen",

year = "1966",

month = oct,

doi = "10.1021/ic50044a022",

language = "אנגלית",

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pages = "1740--1743",

journal = "Inorganic Chemistry",

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AU - Cohen, Donald

PY - 1966/10

Y1 - 1966/10

N2 - Americium perxenate has been prepared by precipitation from basic solutions of americium(III). The compound is orange and shows the characteristic absorption bands of Am(III) in the visible and near-infrared regions, as well as the characteristic infrared absorption at 650-680 cm−1 for the Xe-O vibration in perxenate. The compound is highly hydrated and has the stoichiometric composition Am4(XeO6)340H2O. Its solubility in water is 4.6 X 10−5 M. The compound dissolves in acid to form Am(VI) and Am(V).

AB - Americium perxenate has been prepared by precipitation from basic solutions of americium(III). The compound is orange and shows the characteristic absorption bands of Am(III) in the visible and near-infrared regions, as well as the characteristic infrared absorption at 650-680 cm−1 for the Xe-O vibration in perxenate. The compound is highly hydrated and has the stoichiometric composition Am4(XeO6)340H2O. Its solubility in water is 4.6 X 10−5 M. The compound dissolves in acid to form Am(VI) and Am(V).

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Americium(III) Perxenate

Abstract

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