An Fe(CO)5-thermolysis-based process for the preparation of polymer@iron composite powders with high corrosion resistance

Guy Nesher; Gad Marom; David Avnir

doi:10.1002/ejic.201200086

An Fe(CO)₅-thermolysis-based process for the preparation of polymer@iron composite powders with high corrosion resistance

Guy Nesher, Gad Marom^*, David Avnir

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A new method for the preparation of metal-polymer composite materials is described. This new approach of doping of metals is based on the thermolysis of a zero-valent complex. Specifically, several polymer@Fe-composite powders were prepared and fully characterized. Iron doped with polydimethylsiloxane showed remarkable stability to air oxidation and to corrosion under simulated seawater conditions. A corrosion-proof polymer@iron composite was obtained by thermolysis of Fe(CO)₅. This work adds to the diversity of applications demonstrated for the new field of entrapment of polymers within metal matrices.

Original language	English
Pages (from-to)	5276-5281
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	32
DOIs	https://doi.org/10.1002/ejic.201200086
State	Published - Nov 2012

Keywords

Composite materials
Corrosion inhibition
Doping
Iron
Materials science

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10.1002/ejic.201200086

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title = "An Fe(CO)5-thermolysis-based process for the preparation of polymer@iron composite powders with high corrosion resistance",

abstract = "A new method for the preparation of metal-polymer composite materials is described. This new approach of doping of metals is based on the thermolysis of a zero-valent complex. Specifically, several polymer@Fe-composite powders were prepared and fully characterized. Iron doped with polydimethylsiloxane showed remarkable stability to air oxidation and to corrosion under simulated seawater conditions. A corrosion-proof polymer@iron composite was obtained by thermolysis of Fe(CO)5. This work adds to the diversity of applications demonstrated for the new field of entrapment of polymers within metal matrices.",

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N2 - A new method for the preparation of metal-polymer composite materials is described. This new approach of doping of metals is based on the thermolysis of a zero-valent complex. Specifically, several polymer@Fe-composite powders were prepared and fully characterized. Iron doped with polydimethylsiloxane showed remarkable stability to air oxidation and to corrosion under simulated seawater conditions. A corrosion-proof polymer@iron composite was obtained by thermolysis of Fe(CO)5. This work adds to the diversity of applications demonstrated for the new field of entrapment of polymers within metal matrices.

AB - A new method for the preparation of metal-polymer composite materials is described. This new approach of doping of metals is based on the thermolysis of a zero-valent complex. Specifically, several polymer@Fe-composite powders were prepared and fully characterized. Iron doped with polydimethylsiloxane showed remarkable stability to air oxidation and to corrosion under simulated seawater conditions. A corrosion-proof polymer@iron composite was obtained by thermolysis of Fe(CO)5. This work adds to the diversity of applications demonstrated for the new field of entrapment of polymers within metal matrices.

KW - Composite materials

KW - Corrosion inhibition

KW - Doping

KW - Iron

KW - Materials science

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JF - European Journal of Inorganic Chemistry

IS - 32

ER -

An Fe(CO)₅-thermolysis-based process for the preparation of polymer@iron composite powders with high corrosion resistance

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Keywords

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