An in situ ESR study of the intercalation mechanism: HOPG/fluorine and HOPG/HNO3

I. Palchan; D. Davidov; V. Zevin; G. Polatsek; H. Selig

doi:10.1016/0379-6779(85)90144-4

An in situ ESR study of the intercalation mechanism: HOPG/fluorine and HOPG/HNO₃

I. Palchan^*
, D. Davidov
, V. Zevin
, G. Polatsek
, H. Selig

^*Corresponding author for this work

Racah Institute of Physics

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

An in situ ESR study of Highly Oriented Pyrolytic Graphite (HOPG) indicates dramatic changes in the ESR lineshape (A/B ratio) and intensity upon exposure to fluorine or HNO₃. The results can be interpreted by the formation of a macroscopic intercalation layer and the advance of the boundary separating this layer from the as yet unintercalated HOPG. The measurements yield the diffusion coefficients during the intercalation process.

Original language	English
Pages (from-to)	413-418
Number of pages	6
Journal	Synthetic Metals
Volume	12
Issue number	1-2
DOIs	https://doi.org/10.1016/0379-6779(85)90144-4
State	Published - 1985

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title = "An in situ ESR study of the intercalation mechanism: HOPG/fluorine and HOPG/HNO3",

abstract = "An in situ ESR study of Highly Oriented Pyrolytic Graphite (HOPG) indicates dramatic changes in the ESR lineshape (A/B ratio) and intensity upon exposure to fluorine or HNO3. The results can be interpreted by the formation of a macroscopic intercalation layer and the advance of the boundary separating this layer from the as yet unintercalated HOPG. The measurements yield the diffusion coefficients during the intercalation process.",

author = "I. Palchan and D. Davidov and V. Zevin and G. Polatsek and H. Selig",

year = "1985",

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AU - Palchan, I.

AU - Davidov, D.

AU - Zevin, V.

AU - Polatsek, G.

AU - Selig, H.

PY - 1985

Y1 - 1985

N2 - An in situ ESR study of Highly Oriented Pyrolytic Graphite (HOPG) indicates dramatic changes in the ESR lineshape (A/B ratio) and intensity upon exposure to fluorine or HNO3. The results can be interpreted by the formation of a macroscopic intercalation layer and the advance of the boundary separating this layer from the as yet unintercalated HOPG. The measurements yield the diffusion coefficients during the intercalation process.

AB - An in situ ESR study of Highly Oriented Pyrolytic Graphite (HOPG) indicates dramatic changes in the ESR lineshape (A/B ratio) and intensity upon exposure to fluorine or HNO3. The results can be interpreted by the formation of a macroscopic intercalation layer and the advance of the boundary separating this layer from the as yet unintercalated HOPG. The measurements yield the diffusion coefficients during the intercalation process.

UR - https://www.scopus.com/pages/publications/0022151277

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JF - Synthetic Metals

IS - 1-2

ER -

An in situ ESR study of the intercalation mechanism: HOPG/fluorine and HOPG/HNO₃

Abstract

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