An unusual chlorination of 1-phenyl-4-(2,6-dichlorophenyl)-1,3-butadiene

Md Abul Hashem; Peter Weyerstahl; Bernard S. Green

doi:10.1016/0040-4020(84)85122-4

An unusual chlorination of 1-phenyl-4-(2,6-dichlorophenyl)-1,3-butadiene

Md Abul Hashem^*, Peter Weyerstahl, Bernard S. Green

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

The diene 1a reacted with CHCl₃/aq. NaOH/PTC in CH₂ Cl₂ unexpectedly to give a mixture of the chlorination products 2 and 3a. Usual chlorination with Cl₂ yielded similarly 2, 3a, and 3b dependent on the amount of Cl₂. The formation of 2 as well as the reaction of 7 to give 9 (besides 8) shows an unusual Cl-Cl-interaction.

Original language	English
Pages (from-to)	211-213
Number of pages	3
Journal	Tetrahedron
Volume	40
Issue number	1
DOIs	https://doi.org/10.1016/0040-4020(84)85122-4
State	Published - 1984
Externally published	Yes

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10.1016/0040-4020(84)85122-4

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title = "An unusual chlorination of 1-phenyl-4-(2,6-dichlorophenyl)-1,3-butadiene",

abstract = "The diene 1a reacted with CHCl3/aq. NaOH/PTC in CH2 Cl2 unexpectedly to give a mixture of the chlorination products 2 and 3a. Usual chlorination with Cl2 yielded similarly 2, 3a, and 3b dependent on the amount of Cl2. The formation of 2 as well as the reaction of 7 to give 9 (besides 8) shows an unusual Cl-Cl-interaction.",

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AU - Weyerstahl, Peter

AU - Green, Bernard S.

PY - 1984

Y1 - 1984

N2 - The diene 1a reacted with CHCl3/aq. NaOH/PTC in CH2 Cl2 unexpectedly to give a mixture of the chlorination products 2 and 3a. Usual chlorination with Cl2 yielded similarly 2, 3a, and 3b dependent on the amount of Cl2. The formation of 2 as well as the reaction of 7 to give 9 (besides 8) shows an unusual Cl-Cl-interaction.

AB - The diene 1a reacted with CHCl3/aq. NaOH/PTC in CH2 Cl2 unexpectedly to give a mixture of the chlorination products 2 and 3a. Usual chlorination with Cl2 yielded similarly 2, 3a, and 3b dependent on the amount of Cl2. The formation of 2 as well as the reaction of 7 to give 9 (besides 8) shows an unusual Cl-Cl-interaction.

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ER -

An unusual chlorination of 1-phenyl-4-(2,6-dichlorophenyl)-1,3-butadiene

Abstract

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