Analyses of photoinitiated H+CO2 reactions: Gas phase single-collision conditions and CO2HBr adducts

C. Wittig; Y. M. Engel; R. D. Levine

doi:10.1016/0009-2614(88)85234-5

Analyses of photoinitiated H+CO₂ reactions: Gas phase single-collision conditions and CO₂HBr adducts

C. Wittig^*
, Y. M. Engel
, R. D. Levine

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Analyses of data obtained under single-collision bulk conditions and from CO₂HBr complexes suggest that with complexes ≈80% of the OHproduct accrues via a mechanism wherein repulsive entrance-channel interactions enhance Br-HOCO^† c.m. kinetic energy at the expense of HOCO^† internal energy. Resonances are described in which H is localized between Br and OCO until the reactive window opens.

Original language	English
Pages (from-to)	411-416
Number of pages	6
Journal	Chemical Physics Letters
Volume	153
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(88)85234-5
State	Published - 23 Dec 1988

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title = "Analyses of photoinitiated H+CO2 reactions: Gas phase single-collision conditions and CO2HBr adducts",

abstract = "Analyses of data obtained under single-collision bulk conditions and from CO2HBr complexes suggest that with complexes ≈80\% of the OHproduct accrues via a mechanism wherein repulsive entrance-channel interactions enhance Br-HOCO† c.m. kinetic energy at the expense of HOCO† internal energy. Resonances are described in which H is localized between Br and OCO until the reactive window opens.",

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T2 - Gas phase single-collision conditions and CO2HBr adducts

AU - Wittig, C.

AU - Engel, Y. M.

AU - Levine, R. D.

PY - 1988/12/23

Y1 - 1988/12/23

N2 - Analyses of data obtained under single-collision bulk conditions and from CO2HBr complexes suggest that with complexes ≈80% of the OHproduct accrues via a mechanism wherein repulsive entrance-channel interactions enhance Br-HOCO† c.m. kinetic energy at the expense of HOCO† internal energy. Resonances are described in which H is localized between Br and OCO until the reactive window opens.

AB - Analyses of data obtained under single-collision bulk conditions and from CO2HBr complexes suggest that with complexes ≈80% of the OHproduct accrues via a mechanism wherein repulsive entrance-channel interactions enhance Br-HOCO† c.m. kinetic energy at the expense of HOCO† internal energy. Resonances are described in which H is localized between Br and OCO until the reactive window opens.

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Analyses of photoinitiated H+CO₂ reactions: Gas phase single-collision conditions and CO₂HBr adducts

Abstract

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