Anhydrous chromous acetate revisited - A very simple synthetic route

Ophir Levy; Benny Bogoslavsky; Avi Bino

doi:10.1016/j.ica.2012.04.029

Anhydrous chromous acetate revisited - A very simple synthetic route

Ophir Levy
, Benny Bogoslavsky
, Avi Bino^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

We report the synthesis of crystalline anhydrous dichromium(II) tetraacetate by a one-pot reaction in which chromium metal reacts in the open with a mixture that comprises acetic acid, acetic anhydride and hydrobromic acid. This new route is much superior to all previous multi-step synthetic procedures that involve strict anaerobic conditions or expensive and flammable starting materials.

Original language	English
Pages (from-to)	179-181
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	391
DOIs	https://doi.org/10.1016/j.ica.2012.04.029
State	Published - 30 Aug 2012

Keywords

Chromium
Chromium(II) acetate
Cr(II) complexes
Metal-metal bond
Synthetic methods
X-ray diffraction

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10.1016/j.ica.2012.04.029

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abstract = "We report the synthesis of crystalline anhydrous dichromium(II) tetraacetate by a one-pot reaction in which chromium metal reacts in the open with a mixture that comprises acetic acid, acetic anhydride and hydrobromic acid. This new route is much superior to all previous multi-step synthetic procedures that involve strict anaerobic conditions or expensive and flammable starting materials.",

keywords = "Chromium, Chromium(II) acetate, Cr(II) complexes, Metal-metal bond, Synthetic methods, X-ray diffraction",

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T1 - Anhydrous chromous acetate revisited - A very simple synthetic route

AU - Levy, Ophir

AU - Bogoslavsky, Benny

AU - Bino, Avi

PY - 2012/8/30

Y1 - 2012/8/30

N2 - We report the synthesis of crystalline anhydrous dichromium(II) tetraacetate by a one-pot reaction in which chromium metal reacts in the open with a mixture that comprises acetic acid, acetic anhydride and hydrobromic acid. This new route is much superior to all previous multi-step synthetic procedures that involve strict anaerobic conditions or expensive and flammable starting materials.

AB - We report the synthesis of crystalline anhydrous dichromium(II) tetraacetate by a one-pot reaction in which chromium metal reacts in the open with a mixture that comprises acetic acid, acetic anhydride and hydrobromic acid. This new route is much superior to all previous multi-step synthetic procedures that involve strict anaerobic conditions or expensive and flammable starting materials.

KW - Chromium

KW - Chromium(II) acetate

KW - Cr(II) complexes

KW - Metal-metal bond

KW - Synthetic methods

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84863005516

U2 - 10.1016/j.ica.2012.04.029

DO - 10.1016/j.ica.2012.04.029

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AN - SCOPUS:84863005516

SN - 0020-1693

VL - 391

SP - 179

EP - 181

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Anhydrous chromous acetate revisited - A very simple synthetic route

Abstract

Keywords

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