Anilinium Montmorillonites and the Formation of Ammonium/Amine Associations

Lisa Heller*, S. Yariv

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The IR spectra, X‐ray patterns and DTA curves of various aryl ammonium montmorillonites, are characterized. Depending upon the particular amine, the aryl ammonium ions react with excess base by (1) showing a proton equally between two amine molecules through a water bridge, (2) by retaining the proton identified with one molecule, or (3) by polymerization liberating protons. It is inferred that interlayer alkyl ammonium ions also show protons with excess amine through water bridges but the stability of the aryl and alkyl compounds differs greatly.

Original languageEnglish
Pages (from-to)391-397
Number of pages7
JournalIsrael Journal of Chemistry
Volume8
Issue number3
DOIs
StatePublished - 1970

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