TY - JOUR
T1 - Anilinium Montmorillonites and the Formation of Ammonium/Amine Associations
AU - Heller, Lisa
AU - Yariv, S.
PY - 1970
Y1 - 1970
N2 - The IR spectra, X‐ray patterns and DTA curves of various aryl ammonium montmorillonites, are characterized. Depending upon the particular amine, the aryl ammonium ions react with excess base by (1) showing a proton equally between two amine molecules through a water bridge, (2) by retaining the proton identified with one molecule, or (3) by polymerization liberating protons. It is inferred that interlayer alkyl ammonium ions also show protons with excess amine through water bridges but the stability of the aryl and alkyl compounds differs greatly.
AB - The IR spectra, X‐ray patterns and DTA curves of various aryl ammonium montmorillonites, are characterized. Depending upon the particular amine, the aryl ammonium ions react with excess base by (1) showing a proton equally between two amine molecules through a water bridge, (2) by retaining the proton identified with one molecule, or (3) by polymerization liberating protons. It is inferred that interlayer alkyl ammonium ions also show protons with excess amine through water bridges but the stability of the aryl and alkyl compounds differs greatly.
UR - http://www.scopus.com/inward/record.url?scp=84991176435&partnerID=8YFLogxK
U2 - 10.1002/ijch.197000045
DO - 10.1002/ijch.197000045
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AN - SCOPUS:84991176435
SN - 0021-2148
VL - 8
SP - 391
EP - 397
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
IS - 3
ER -