Anion exchange of metal complexes-XVIII. Sorption of metal ions from anhydrous, chloride-containing, methanol and ethanol

The distribution of tracer concentrations of rhenium(VII), copper(II), cadmium(II) and iron(III) between Dowex-1 anion exchanger and anhydrous methanol and ethanol solutions of hydrogen chloride and tetra methylammonium chloride has been studied. The effect of low (2 wt.%) concentrations of water on the distribution of copper(II) in ethanolic hydrogen chloride was shown to be small. The loading of copper(II) chloride at macro concentrations, with no excess chloride present, has also been measured for methanol, ethanol and acetone solutions. Some conclusions concerning the species formed in the resin and in the solutions could be reached.