Anionic graft polymerization of acrylonitrile and methacrylonitrile on cellulose acetate

Yair Avny; Baruch Yom‐Tov; Albert Zilkha

doi:10.1002/app.1965.070091120

Anionic graft polymerization of acrylonitrile and methacrylonitrile on cellulose acetate

Yair Avny^*
, Baruch Yom‐Tov
, Albert Zilkha

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The anionic graft polymerization of AN and MAN on cellulose acetate alkoxide derivative (Li, Na, K) was investigated in THF, DMF, and DMSO. Although the yield of the polymerization was high the extent of grafting of acrylonitrile was low (1.4–5.3% in DMF and DMSO and 20% in THF) due to homopolymerization caused by chain transfer to monomer. With methacrylonitrile which has no acidic α‐hydrogen the amount of grafted monomer was higher (37–72%).

Original language	English
Pages (from-to)	3737-3743
Number of pages	7
Journal	Journal of Applied Polymer Science
Volume	9
Issue number	11
DOIs	https://doi.org/10.1002/app.1965.070091120
State	Published - Nov 1965

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title = "Anionic graft polymerization of acrylonitrile and methacrylonitrile on cellulose acetate",

abstract = "The anionic graft polymerization of AN and MAN on cellulose acetate alkoxide derivative (Li, Na, K) was investigated in THF, DMF, and DMSO. Although the yield of the polymerization was high the extent of grafting of acrylonitrile was low (1.4–5.3\% in DMF and DMSO and 20\% in THF) due to homopolymerization caused by chain transfer to monomer. With methacrylonitrile which has no acidic α‐hydrogen the amount of grafted monomer was higher (37–72\%).",

author = "Yair Avny and Baruch Yom‐Tov and Albert Zilkha",

year = "1965",

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AU - Avny, Yair

AU - Yom‐Tov, Baruch

AU - Zilkha, Albert

PY - 1965/11

Y1 - 1965/11

N2 - The anionic graft polymerization of AN and MAN on cellulose acetate alkoxide derivative (Li, Na, K) was investigated in THF, DMF, and DMSO. Although the yield of the polymerization was high the extent of grafting of acrylonitrile was low (1.4–5.3% in DMF and DMSO and 20% in THF) due to homopolymerization caused by chain transfer to monomer. With methacrylonitrile which has no acidic α‐hydrogen the amount of grafted monomer was higher (37–72%).

AB - The anionic graft polymerization of AN and MAN on cellulose acetate alkoxide derivative (Li, Na, K) was investigated in THF, DMF, and DMSO. Although the yield of the polymerization was high the extent of grafting of acrylonitrile was low (1.4–5.3% in DMF and DMSO and 20% in THF) due to homopolymerization caused by chain transfer to monomer. With methacrylonitrile which has no acidic α‐hydrogen the amount of grafted monomer was higher (37–72%).

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JO - Journal of Applied Polymer Science

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IS - 11

ER -

Anionic graft polymerization of acrylonitrile and methacrylonitrile on cellulose acetate

Abstract

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