Anisotropic localized surface plasmon resonance of vanadium dioxide rods in flexible thermochromic film towards multifunctionality

Qiyang Xu; Yujie Ke; Chengchen Feng; Cong Chen; Zuohao Wen; Haoran Wang; Miaoyang Sun; Xinghai Liu; Hai Liu; Shlomo Magdassi; Houbin Li; Chi Huang; Yi Long

doi:10.1016/j.solmat.2021.111163

Anisotropic localized surface plasmon resonance of vanadium dioxide rods in flexible thermochromic film towards multifunctionality

Qiyang Xu, Yujie Ke^*, Chengchen Feng, Cong Chen, Zuohao Wen, Haoran Wang, Miaoyang Sun, Xinghai Liu^*, Hai Liu, Shlomo Magdassi, Houbin Li, Chi Huang, Yi Long^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Plasmonic thermochromic films are promising for smart window applications. Hereby, we develop a flexible plasmonic thermochromic film towards multifunctionality. The double-layer film consists of a bottom layer of W/Mg co-doped vanadium dioxide (VO₂) rods in a polyurethane acrylate matrix and a top layer of hollow silica spheres (HSSs). Based on the finite-difference time-domain (FDTD) method, we demonstrate for the first time, a transverse and a longitudinal mode of VO₂ localized surface plasmonic resonance (LSPR) in near- and mid-infrared bands, respectively, and only the transverse mode contributes to the solar energy modulation performance. The film shows a luminous transmittance of 46.2%, a solar energy modulation of 10.8%, and a critical transition temperature of 36.9 °C. The HSSs overcoating enhances the surface hydrophilicity and thermal insulation, which give rise to more favored functionalities for windows.

Original language	American English
Article number	111163
Journal	Solar Energy Materials and Solar Cells
Volume	230
DOIs	https://doi.org/10.1016/j.solmat.2021.111163
State	Published - 15 Sep 2021

Bibliographical note

Funding Information:
Q. Xu, Y. Ke, and C. Feng contribute equally. X. Liu acknowledges the support of the National Natural Science Foundation of China (Grant No. 51776143 and U1830127 ) and Fundamental Research Funds for the Central Universities (Grant No. 2042018kf0238 ). The usage of SEM, TEM, and XPS funded by the Open Subsidies for large-scale Equipment of Wuhan University (Grant No. LF20181061). Y. Long thanks to the funding support by the National Research Foundation , Prime Minister's Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme, Sino-Singapore International Joint Research Institute, and Minister of Education Singapore Tier 1 RG86/20 and RG103/19 for funding support.

Publisher Copyright:
© 2021 Elsevier B.V.

Keywords

Smart window
Solar modulation
Surface plasmon resonance
Thermal management
Thermochromics
VO
Wettability

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.solmat.2021.111163

Cite this

Xu, Q., Ke, Y., Feng, C., Chen, C., Wen, Z., Wang, H., Sun, M., Liu, X., Liu, H., Magdassi, S., Li, H., Huang, C., & Long, Y. (2021). Anisotropic localized surface plasmon resonance of vanadium dioxide rods in flexible thermochromic film towards multifunctionality. Solar Energy Materials and Solar Cells, 230, Article 111163. https://doi.org/10.1016/j.solmat.2021.111163

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title = "Anisotropic localized surface plasmon resonance of vanadium dioxide rods in flexible thermochromic film towards multifunctionality",

abstract = "Plasmonic thermochromic films are promising for smart window applications. Hereby, we develop a flexible plasmonic thermochromic film towards multifunctionality. The double-layer film consists of a bottom layer of W/Mg co-doped vanadium dioxide (VO2) rods in a polyurethane acrylate matrix and a top layer of hollow silica spheres (HSSs). Based on the finite-difference time-domain (FDTD) method, we demonstrate for the first time, a transverse and a longitudinal mode of VO2 localized surface plasmonic resonance (LSPR) in near- and mid-infrared bands, respectively, and only the transverse mode contributes to the solar energy modulation performance. The film shows a luminous transmittance of 46.2%, a solar energy modulation of 10.8%, and a critical transition temperature of 36.9 °C. The HSSs overcoating enhances the surface hydrophilicity and thermal insulation, which give rise to more favored functionalities for windows.",

keywords = "Smart window, Solar modulation, Surface plasmon resonance, Thermal management, Thermochromics, VO, Wettability",

author = "Qiyang Xu and Yujie Ke and Chengchen Feng and Cong Chen and Zuohao Wen and Haoran Wang and Miaoyang Sun and Xinghai Liu and Hai Liu and Shlomo Magdassi and Houbin Li and Chi Huang and Yi Long",

note = "Funding Information: Q. Xu, Y. Ke, and C. Feng contribute equally. X. Liu acknowledges the support of the National Natural Science Foundation of China (Grant No. 51776143 and U1830127 ) and Fundamental Research Funds for the Central Universities (Grant No. 2042018kf0238 ). The usage of SEM, TEM, and XPS funded by the Open Subsidies for large-scale Equipment of Wuhan University (Grant No. LF20181061). Y. Long thanks to the funding support by the National Research Foundation , Prime Minister's Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme, Sino-Singapore International Joint Research Institute, and Minister of Education Singapore Tier 1 RG86/20 and RG103/19 for funding support. Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

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doi = "10.1016/j.solmat.2021.111163",

language = "American English",

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AU - Xu, Qiyang

AU - Ke, Yujie

AU - Feng, Chengchen

AU - Chen, Cong

AU - Wen, Zuohao

AU - Wang, Haoran

AU - Sun, Miaoyang

AU - Liu, Xinghai

AU - Liu, Hai

AU - Magdassi, Shlomo

AU - Li, Houbin

AU - Huang, Chi

AU - Long, Yi

N1 - Funding Information: Q. Xu, Y. Ke, and C. Feng contribute equally. X. Liu acknowledges the support of the National Natural Science Foundation of China (Grant No. 51776143 and U1830127 ) and Fundamental Research Funds for the Central Universities (Grant No. 2042018kf0238 ). The usage of SEM, TEM, and XPS funded by the Open Subsidies for large-scale Equipment of Wuhan University (Grant No. LF20181061). Y. Long thanks to the funding support by the National Research Foundation , Prime Minister's Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme, Sino-Singapore International Joint Research Institute, and Minister of Education Singapore Tier 1 RG86/20 and RG103/19 for funding support. Publisher Copyright: © 2021 Elsevier B.V.

PY - 2021/9/15

Y1 - 2021/9/15

N2 - Plasmonic thermochromic films are promising for smart window applications. Hereby, we develop a flexible plasmonic thermochromic film towards multifunctionality. The double-layer film consists of a bottom layer of W/Mg co-doped vanadium dioxide (VO2) rods in a polyurethane acrylate matrix and a top layer of hollow silica spheres (HSSs). Based on the finite-difference time-domain (FDTD) method, we demonstrate for the first time, a transverse and a longitudinal mode of VO2 localized surface plasmonic resonance (LSPR) in near- and mid-infrared bands, respectively, and only the transverse mode contributes to the solar energy modulation performance. The film shows a luminous transmittance of 46.2%, a solar energy modulation of 10.8%, and a critical transition temperature of 36.9 °C. The HSSs overcoating enhances the surface hydrophilicity and thermal insulation, which give rise to more favored functionalities for windows.

AB - Plasmonic thermochromic films are promising for smart window applications. Hereby, we develop a flexible plasmonic thermochromic film towards multifunctionality. The double-layer film consists of a bottom layer of W/Mg co-doped vanadium dioxide (VO2) rods in a polyurethane acrylate matrix and a top layer of hollow silica spheres (HSSs). Based on the finite-difference time-domain (FDTD) method, we demonstrate for the first time, a transverse and a longitudinal mode of VO2 localized surface plasmonic resonance (LSPR) in near- and mid-infrared bands, respectively, and only the transverse mode contributes to the solar energy modulation performance. The film shows a luminous transmittance of 46.2%, a solar energy modulation of 10.8%, and a critical transition temperature of 36.9 °C. The HSSs overcoating enhances the surface hydrophilicity and thermal insulation, which give rise to more favored functionalities for windows.

KW - Smart window

KW - Solar modulation

KW - Surface plasmon resonance

KW - Thermal management

KW - Thermochromics

KW - VO

KW - Wettability

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U2 - 10.1016/j.solmat.2021.111163

DO - 10.1016/j.solmat.2021.111163

M3 - Article

AN - SCOPUS:85106348629

SN - 0927-0248

VL - 230

JO - Solar Energy Materials and Solar Cells

JF - Solar Energy Materials and Solar Cells

M1 - 111163

ER -

Anisotropic localized surface plasmon resonance of vanadium dioxide rods in flexible thermochromic film towards multifunctionality

Abstract

Bibliographical note

Keywords

UN SDGs

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