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Anomalous photovoltaic effect in nanocrystalline SiSi O2 composites

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Abstract

We have observed an anomalous photovoltaic effect in films of Si nanocrystals embedded in Si O2. Using conductive-probe atomic force microscopy and global transport measurements, we found, close to the percolation threshold of the Si crystallite phase, a large photovoltaic effect of up to about 7 V. Following the dependence of this effect on the size of the Si nanocrystals and on the relative tip position with respect to the counterelectrode, we suggest a model based on charge separation of excited electron-hole pairs governed by the size-dependent quantum confinement and charging energies.

Original languageEnglish
Article number112109
JournalApplied Physics Letters
Volume92
Issue number11
DOIs
StatePublished - 2008

Bibliographical note

Funding Information:
This work was supported by the Israel Science Foundation, Centers of Excellence program and by the European Union SA-NANO project.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

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