Antimony doped tin oxide coating of muscovite clays by the Pechini route

Sergey Sladkevich; Nilar Kyi; Jenny Gun; Petr Prikhodchenko; Sergey Ischuk; Ovadia Lev

doi:10.1016/j.tsf.2011.06.107

Antimony doped tin oxide coating of muscovite clays by the Pechini route

Sergey Sladkevich, Nilar Kyi, Jenny Gun, Petr Prikhodchenko, Sergey Ischuk, Ovadia Lev^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The preparation of antimony doped tin oxide (ATO) conductive thin films on mica (muscovite) clays is described. ATO coating solution was prepared from ethylene glycol monomer, citric acid ligand, SbCl₃ and SnCl ₂ precursors in alcohol solution. Muscovite thin film coating was prepared by gradual addition of the precursor solution to a water-muscovite clay dispersion. Under appropriate precursor concentrations and temperature, aggregation of the clays and ATO particles was prevented, and the ATO film grew exclusively on the clay substrate. Heat treatment of the coated mica resulted in semi transparent and conductive clays which could be used for composite film formation. Whereas the Pechini route is widely used for dip coating of ATO films, here we extend the approach for coating particulate matter. The films were characterized by electronic microscopy, X-ray photoelectron spectroscopy, powder diffraction, and thermal analysis and the dependence of conductivity on calcination temperature and precursor concentrations are described.

Original language	English
Pages (from-to)	152-158
Number of pages	7
Journal	Thin Solid Films
Volume	520
Issue number	1
DOIs	https://doi.org/10.1016/j.tsf.2011.06.107
State	Published - 31 Oct 2011

Bibliographical note

Funding Information:
We thank the Israel Ministry of Science , MOS, the Russian Foundation for Basic Research (grants 09-03-12151 , 11-03-00551 , 11-03-92478 ), the Council on Grants of the President of the Russian Federation ( NSh-8503.2010.3 ), the Presidium of the Russian Academy of Sciences and the Ministry of Education and Science of the Russian Federation (Federal Target program “Scientific and Pedagogical Staff of Innovating Russia 2009–2013”, No 16.740.11.0428 ). The authors thank the Singapore National Research Foundation CREATE program ‘Nanomaterials for Energy and Water Management’ for its financial support.

Keywords

Antimony-doped tin oxide
Clays
Muscovite
Pechini route

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abstract = "The preparation of antimony doped tin oxide (ATO) conductive thin films on mica (muscovite) clays is described. ATO coating solution was prepared from ethylene glycol monomer, citric acid ligand, SbCl3 and SnCl 2 precursors in alcohol solution. Muscovite thin film coating was prepared by gradual addition of the precursor solution to a water-muscovite clay dispersion. Under appropriate precursor concentrations and temperature, aggregation of the clays and ATO particles was prevented, and the ATO film grew exclusively on the clay substrate. Heat treatment of the coated mica resulted in semi transparent and conductive clays which could be used for composite film formation. Whereas the Pechini route is widely used for dip coating of ATO films, here we extend the approach for coating particulate matter. The films were characterized by electronic microscopy, X-ray photoelectron spectroscopy, powder diffraction, and thermal analysis and the dependence of conductivity on calcination temperature and precursor concentrations are described.",

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note = "Funding Information: We thank the Israel Ministry of Science , MOS, the Russian Foundation for Basic Research (grants 09-03-12151 , 11-03-00551 , 11-03-92478 ), the Council on Grants of the President of the Russian Federation ( NSh-8503.2010.3 ), the Presidium of the Russian Academy of Sciences and the Ministry of Education and Science of the Russian Federation (Federal Target program “Scientific and Pedagogical Staff of Innovating Russia 2009–2013”, No 16.740.11.0428 ). The authors thank the Singapore National Research Foundation CREATE program {\textquoteleft}Nanomaterials for Energy and Water Management{\textquoteright} for its financial support.",

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N2 - The preparation of antimony doped tin oxide (ATO) conductive thin films on mica (muscovite) clays is described. ATO coating solution was prepared from ethylene glycol monomer, citric acid ligand, SbCl3 and SnCl 2 precursors in alcohol solution. Muscovite thin film coating was prepared by gradual addition of the precursor solution to a water-muscovite clay dispersion. Under appropriate precursor concentrations and temperature, aggregation of the clays and ATO particles was prevented, and the ATO film grew exclusively on the clay substrate. Heat treatment of the coated mica resulted in semi transparent and conductive clays which could be used for composite film formation. Whereas the Pechini route is widely used for dip coating of ATO films, here we extend the approach for coating particulate matter. The films were characterized by electronic microscopy, X-ray photoelectron spectroscopy, powder diffraction, and thermal analysis and the dependence of conductivity on calcination temperature and precursor concentrations are described.

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Antimony doped tin oxide coating of muscovite clays by the Pechini route

Abstract

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Keywords

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