Antimony tin oxide (ATO) nanoparticle formation from H2O 2 solutions: A new generic film coating from basic solutions

Sergey Sladkevich; Alexey A. Mikhaylov; Petr V. Prikhodchenko; Tatiana A. Tripol'skaya; Ovadia Lev

doi:10.1021/ic1015862

Antimony tin oxide (ATO) nanoparticle formation from H₂O ₂ solutions: A new generic film coating from basic solutions

Sergey Sladkevich
, Alexey A. Mikhaylov
, Petr V. Prikhodchenko
, Tatiana A. Tripol'skaya
, Ovadia Lev^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

A generic method for conductive film coating of minerals and acidsensitive materials by antimony-doped tin oxide (ATO) is introduced. The coating was performed from a hydrogen peroxide stabilized stannate and antimonate precursor solution. This is the first demonstration of ATO coating from an organic ligand-free solution. Uniform coating of different clays and other irregular configurations by monosized 5 nm ATO particles was demonstrated. The deposition mechanism and the observed preference for mineral surface coating over homogeneous agglomeration of the tin oxide particles are explained by a hydrogen peroxide capping mechanism and hydrogen bonding of the hydroperoxo nanoparticles to the H₂O₂-activated mineral surfaces.

Original language	English
Pages (from-to)	9110-9112
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	20
DOIs	https://doi.org/10.1021/ic1015862
State	Published - 18 Oct 2010

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title = "Antimony tin oxide (ATO) nanoparticle formation from H2O 2 solutions: A new generic film coating from basic solutions",

abstract = "A generic method for conductive film coating of minerals and acidsensitive materials by antimony-doped tin oxide (ATO) is introduced. The coating was performed from a hydrogen peroxide stabilized stannate and antimonate precursor solution. This is the first demonstration of ATO coating from an organic ligand-free solution. Uniform coating of different clays and other irregular configurations by monosized 5 nm ATO particles was demonstrated. The deposition mechanism and the observed preference for mineral surface coating over homogeneous agglomeration of the tin oxide particles are explained by a hydrogen peroxide capping mechanism and hydrogen bonding of the hydroperoxo nanoparticles to the H2O2-activated mineral surfaces.",

author = "Sergey Sladkevich and Mikhaylov, \{Alexey A.\} and Prikhodchenko, \{Petr V.\} and Tripol'skaya, \{Tatiana A.\} and Ovadia Lev",

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doi = "10.1021/ic1015862",

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T1 - Antimony tin oxide (ATO) nanoparticle formation from H2O 2 solutions

T2 - A new generic film coating from basic solutions

AU - Sladkevich, Sergey

AU - Mikhaylov, Alexey A.

AU - Prikhodchenko, Petr V.

AU - Tripol'skaya, Tatiana A.

AU - Lev, Ovadia

PY - 2010/10/18

Y1 - 2010/10/18

N2 - A generic method for conductive film coating of minerals and acidsensitive materials by antimony-doped tin oxide (ATO) is introduced. The coating was performed from a hydrogen peroxide stabilized stannate and antimonate precursor solution. This is the first demonstration of ATO coating from an organic ligand-free solution. Uniform coating of different clays and other irregular configurations by monosized 5 nm ATO particles was demonstrated. The deposition mechanism and the observed preference for mineral surface coating over homogeneous agglomeration of the tin oxide particles are explained by a hydrogen peroxide capping mechanism and hydrogen bonding of the hydroperoxo nanoparticles to the H2O2-activated mineral surfaces.

AB - A generic method for conductive film coating of minerals and acidsensitive materials by antimony-doped tin oxide (ATO) is introduced. The coating was performed from a hydrogen peroxide stabilized stannate and antimonate precursor solution. This is the first demonstration of ATO coating from an organic ligand-free solution. Uniform coating of different clays and other irregular configurations by monosized 5 nm ATO particles was demonstrated. The deposition mechanism and the observed preference for mineral surface coating over homogeneous agglomeration of the tin oxide particles are explained by a hydrogen peroxide capping mechanism and hydrogen bonding of the hydroperoxo nanoparticles to the H2O2-activated mineral surfaces.

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JO - Inorganic Chemistry

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IS - 20

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Antimony tin oxide (ATO) nanoparticle formation from H₂O ₂ solutions: A new generic film coating from basic solutions

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