Assembly of Bottlebrush Block Copolymers and Nanoparticles in Ultrathin Films: Effect of Substrate-Copolymer Interaction on the Nanocomposite Morphology

Yaron Aviv, Esra Altay, Javid Rzayev*, Roy Shenhar*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Bottlebrush block copolymers (BBCPs) offer unique advantages for polymer-nanoparticle (NP) assembly, arising from the stiffness of their backbones and the compositional tunability afforded by the lengths of the grafts in each block independently. The morphologies of ultrathin BBCP films are extremely sensitive to the chemistry of the substrate. Modifying the substrate with a polymer brush that corresponds to one of the blocks of the bottlebrush copolymer leads to different, often nonbulk morphologies that relate to the interaction of the copolymer with the substrate, which is dictated by the bottlebrush polymer composition. In this work, we investigate the assembly of BBCPs of different compositions with gold NPs, which are modified with polymeric ligands that correspond to one of the blocks. Our results show that the net interaction of the copolymer with the substrate influences the self-assembly process, leading to two types of routes: the co-assembly route, in which the NPs are organized by the polymer into periodic structures, or macrophase separation. In the co-assembly route, selective substrates slightly distort the shape of the domains. The NPs, in turn, influence the kinetics of the process by their interaction with the substrate.

Original languageAmerican English
Pages (from-to)6247-6256
Number of pages10
JournalMacromolecules
Volume54
Issue number13
DOIs
StatePublished - 13 Jul 2021

Bibliographical note

Publisher Copyright:
© 2021 American Chemical Society.

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