TY - JOUR
T1 - BET modeling of solid-liquid phase diagrams of common ion binary salt hydrate mixtures. I. The BET parameters
AU - Marcus, Y.
PY - 2005/3
Y1 - 2005/3
N2 - Solid-liquid phase diagrams of binary salt hydrate mixtures can be modeled by means of the BET method, next paper, which considers the water as if it were "adsorbed" on "sites" of the salt. The parameter r describes the average number of sites and ε describes the molar enthalpy of adsorption in excess of the enthalpy of condensation of water vapor. The BET parameters r and ε required for the modeling were obtained for a large number of salts from water activities or related quantities of concentrated aqueous solutions of them. This paper consists of a comprehensive compilation of these two BET parameters for a large number of salts.
AB - Solid-liquid phase diagrams of binary salt hydrate mixtures can be modeled by means of the BET method, next paper, which considers the water as if it were "adsorbed" on "sites" of the salt. The parameter r describes the average number of sites and ε describes the molar enthalpy of adsorption in excess of the enthalpy of condensation of water vapor. The BET parameters r and ε required for the modeling were obtained for a large number of salts from water activities or related quantities of concentrated aqueous solutions of them. This paper consists of a comprehensive compilation of these two BET parameters for a large number of salts.
KW - BET method
KW - Concentrated aqueous electrolytes
KW - Modeling
KW - Phase diagram
UR - http://www.scopus.com/inward/record.url?scp=33847058739&partnerID=8YFLogxK
U2 - 10.1007/s10953-005-3050-3
DO - 10.1007/s10953-005-3050-3
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AN - SCOPUS:33847058739
SN - 0095-9782
VL - 34
SP - 297
EP - 306
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
IS - 3
ER -