Bicorannulenyl: Stereochemistry of a C₄₀H₁₈ biaryl composed of two chiral bowls

Keyphrases

• Enantiomerization 100%
• Stereochemistry 100%
• Biaryls 100%
• Transition State 66%
• Achiral 66%
• DFT Calculations 33%
• Solid State 33%
• Multi-step Process 33%
• Dynamic Stereochemistry 33%
• Single Crystal X-ray Diffraction (SCXRD) 33%
• Chirality 33%
• Stereochemical Hypothesis 33%
• Single Bond 33%
• Buckybowls 33%
• Bond Rotation 33%
• Bowl Inversion 33%
• DFT Results 33%
• Variable Temperature NMR Spectroscopy 33%
• Packing Mode 33%

Chemistry

• Density Functional Theory 100%
• Transition State 100%
• Stereochemistry 100%
• Biaryl 100%
• Conformational Isomer 50%
• NMR Spectroscopy 50%
• Single Crystal X-Ray Diffraction 50%
• Chirality 50%
• Single Bond 50%
• Bond Rotation 50%