TY - JOUR
T1 - Bromide-chloride exchange between alkyl halides and metal halide salts under phase transfer conditions
AU - Sasson, Y.
AU - Weiss, M.
AU - Loupy, A.
AU - Bram, G.
AU - Pardo, C.
PY - 1986
Y1 - 1986
N2 - The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.
AB - The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.
UR - http://www.scopus.com/inward/record.url?scp=37049067884&partnerID=8YFLogxK
U2 - 10.1039/C39860001250
DO - 10.1039/C39860001250
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AN - SCOPUS:37049067884
SN - 0022-4936
SP - 1250
EP - 1252
JO - Chemical Communications
JF - Chemical Communications
IS - 16
ER -