Bromide-chloride exchange between alkyl halides and metal halide salts under phase transfer conditions

Y. Sasson; M. Weiss; A. Loupy; G. Bram; C. Pardo

doi:10.1039/C39860001250

Bromide-chloride exchange between alkyl halides and metal halide salts under phase transfer conditions

Y. Sasson^*
, M. Weiss
, A. Loupy
, G. Bram
, C. Pardo

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.

Original language	English
Pages (from-to)	1250-1252
Number of pages	3
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39860001250
State	Published - 1986

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title = "Bromide-chloride exchange between alkyl halides and metal halide salts under phase transfer conditions",

abstract = "The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.",

author = "Y. Sasson and M. Weiss and A. Loupy and G. Bram and C. Pardo",

year = "1986",

doi = "10.1039/C39860001250",

language = "אנגלית",

pages = "1250--1252",

journal = "Journal of the Chemical Society D: Chemical Communications",

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publisher = "Chemical Society",

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T1 - Bromide-chloride exchange between alkyl halides and metal halide salts under phase transfer conditions

AU - Sasson, Y.

AU - Weiss, M.

AU - Loupy, A.

AU - Bram, G.

AU - Pardo, C.

PY - 1986

Y1 - 1986

N2 - The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.

AB - The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr + MCl where R = primary alkyl group and M = Li, Na, K, Ca is strongly dependent on the nature of the metal cation M and the amount of water present in the reaction mixture; this has been applied in the synthetic use of the reaction in both directions.

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AN - SCOPUS:37049067884

SN - 0022-4936

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 16

ER -

Bromide-chloride exchange between alkyl halides and metal halide salts under phase transfer conditions

Abstract

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