Calcite dissolution rates in texturally diverse calcareous rocks

Yael Levenson, May Schiller, Yevgeny Kreisserman, Simon Emmanuel*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

The injection of reactive fluids into carbonate reservoirs during enhanced recovery operations can induce important changes in rock permeability. However, reliably predicting these changes requires accurate knowledge of calcite reaction rates. While numerous studies have examined calcium carbonate dissolution rates, most have focused on pure calcite crystals rather than actual rocks. In this study, two types of flow-through experiments were carried out to determine the calcite dissolution rates in texturally diverse calcareous rocks: the first type of experiment had a duration of 3 days, while the second type ran for 3 months. Our experiments show that rocks with differing textures and roughness (samples included coarse-grained oolitic limestone, fine-grained Solnhofen limestone, marble and calcite spar) do in fact dissolve by different mechanisms. However, despite these differences, bulk reaction rates were found to be remarkably similar (with a relative standard deviation of <20%) and consistent with previously reported reaction rates for calcite. Thus, our results suggest that textural differences between rock types are unlikely to have an important impact on overall reaction rates in fractured carbonate reservoirs.

Original languageAmerican English
Pages (from-to)81-94
Number of pages14
JournalGeological Society Special Publication
Volume406
Issue number1
DOIs
StatePublished - 24 May 2015

Bibliographical note

Publisher Copyright:
© The Geological Society of London 2015.

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