Calix[6]arene Derivatives with Differently Modified Bridges

Ori Shalev, Silvio E. Biali*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

A calix[6]arene derivative where all methylene bridges have been formally replaced by two different types of groups (carbonyl and bromomethylene, 7), was prepared via bromination (NBS, CH2Cl2, irradiation) of a diketocalix[6]arene. Reaction of all-trans 7 with MeOH afforded the all-trans decamethoxy ether calix[6]arene derivative.

Original languageAmerican English
Pages (from-to)749-752
Number of pages4
JournalEuropean Journal of Organic Chemistry
Volume2020
Issue number6
DOIs
StatePublished - 14 Feb 2020

Bibliographical note

Publisher Copyright:
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

  • Calixarenes
  • Conformational analysis
  • Halogenation
  • Macrocycles
  • Stereochemistry

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