Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands

Ilya Kisets, Dmitri Gelman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

New air-stable tripodal triphosphine ligands 1,8,13-tris(diisopropylphosphino)-2,3-dimethoxytriptycene (P3T1) and 1,8,13-tris(diphenylphosphino)-2,3-dimethoxytriptycene (P3T2) are presented and discussed. Their synthesis is based on the first practical synthesis of 1,8,13-tribromotriptycene. Reaction with palladium leads to the formation of new pseudo-C3-symmetric carbometalated complexes: namely, Pd(P3T1)Cl and Pd(P3T2)Cl. The catalytic activity of the new ligands and complexes was tested in the palladium-catalyzed chemoselective transfer hydrogenation of α,β-unsaturated ketones.

Original languageAmerican English
Pages (from-to)526-529
Number of pages4
JournalOrganometallics
Volume37
Issue number4
DOIs
StatePublished - 26 Feb 2018

Bibliographical note

Publisher Copyright:
© 2018 American Chemical Society.

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