Cation-cation bonding in nitrenium metal complexes

Yuri Tulchinsky; Sebastian Kozuch; Prasenjit Saha; Mark Botoshansky; Linda J.W. Shimon; Mark Gandelman

doi:10.1039/c3sc53083c

Cation-cation bonding in nitrenium metal complexes

Yuri Tulchinsky, Sebastian Kozuch, Prasenjit Saha, Mark Botoshansky, Linda J.W. Shimon, Mark Gandelman^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Nitrenium ligands provide an excellent platform for the straightforward and efficient synthesis of extremely rare complexes that possess positively charged ligands coordinated to positively charged metals. Examples of stable cation-cation and cation-dication coordination bonds are demonstrated. Computational studies show that such bonding is greatly stabilized by its incorporation into a tridentate frame, as well as the use of polar solvents.

Original language	English
Pages (from-to)	1305-1311
Number of pages	7
Journal	Chemical Science
Volume	5
Issue number	4
DOIs	https://doi.org/10.1039/c3sc53083c
State	Published - Apr 2014
Externally published	Yes

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AU - Gandelman, Mark

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AB - Nitrenium ligands provide an excellent platform for the straightforward and efficient synthesis of extremely rare complexes that possess positively charged ligands coordinated to positively charged metals. Examples of stable cation-cation and cation-dication coordination bonds are demonstrated. Computational studies show that such bonding is greatly stabilized by its incorporation into a tridentate frame, as well as the use of polar solvents.

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Cation-cation bonding in nitrenium metal complexes

Abstract

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