Cation-cation bonding in nitrenium metal complexes

Yuri Tulchinsky, Sebastian Kozuch, Prasenjit Saha, Mark Botoshansky, Linda J.W. Shimon, Mark Gandelman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

Nitrenium ligands provide an excellent platform for the straightforward and efficient synthesis of extremely rare complexes that possess positively charged ligands coordinated to positively charged metals. Examples of stable cation-cation and cation-dication coordination bonds are demonstrated. Computational studies show that such bonding is greatly stabilized by its incorporation into a tridentate frame, as well as the use of polar solvents.

Original languageAmerican English
Pages (from-to)1305-1311
Number of pages7
JournalChemical Science
Volume5
Issue number4
DOIs
StatePublished - Apr 2014
Externally publishedYes

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