TY - JOUR
T1 - CD additivity in trichothecene benzoates
T2 - application as a microanalytical method for trichothecene characterization
AU - Oltz, Eugene M.
AU - Nakanishi, Koji
AU - Yagen, Boris
AU - Corley, David G.
AU - Rottinghaus, George E.
AU - Tempesta, Michael S.
PY - 1986
Y1 - 1986
N2 - The additivity relation in A values of split CD curves previously established with pyranose p-bromobenzoates was shown to be valid for p-bromobenzoates of the cage-like trichothecene system (which also possesses a primary hydroxyl group). This suggests that additivity is generally valid even for congested multichromophoric molecules. The relation has been integrated Into a new micro method for trichothecene characterization, which was applied to a new trichothecene from Fusarium sporotrichioides (MC-72083) at a sub- μg level.
AB - The additivity relation in A values of split CD curves previously established with pyranose p-bromobenzoates was shown to be valid for p-bromobenzoates of the cage-like trichothecene system (which also possesses a primary hydroxyl group). This suggests that additivity is generally valid even for congested multichromophoric molecules. The relation has been integrated Into a new micro method for trichothecene characterization, which was applied to a new trichothecene from Fusarium sporotrichioides (MC-72083) at a sub- μg level.
UR - http://www.scopus.com/inward/record.url?scp=0022541858&partnerID=8YFLogxK
U2 - 10.1016/S0040-4020(01)90546-0
DO - 10.1016/S0040-4020(01)90546-0
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:0022541858
SN - 0040-4020
VL - 42
SP - 2615
EP - 2624
JO - Tetrahedron
JF - Tetrahedron
IS - 10
ER -