Ce3+ as a probe of the crystal field and the nature of the impurity-ligand bond in borate and phosphate glasses

Renata Reisfeld; J. Hormodaly; Baruch Barnett

doi:10.1016/0009-2614(72)87066-0

Ce³⁺ as a probe of the crystal field and the nature of the impurity-ligand bond in borate and phosphate glasses

Renata Reisfeld^*, J. Hormodaly, Baruch Barnett

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

From the optical absorption spectrum of Ce³⁺ in borate and phosphate glasses, we calculate the nephelauxetic effect in the 4f-5d transition and the crystal field strength in these hosts. Some effects of covalency on the Ce³⁺-ligand bond are discussed and the bond-forming f-orbitals suggested.

Original language	English
Pages (from-to)	248-251
Number of pages	4
Journal	Chemical Physics Letters
Volume	17
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(72)87066-0
State	Published - 15 Nov 1972

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title = "Ce3+ as a probe of the crystal field and the nature of the impurity-ligand bond in borate and phosphate glasses",

abstract = "From the optical absorption spectrum of Ce3+ in borate and phosphate glasses, we calculate the nephelauxetic effect in the 4f-5d transition and the crystal field strength in these hosts. Some effects of covalency on the Ce3+-ligand bond are discussed and the bond-forming f-orbitals suggested.",

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AU - Reisfeld, Renata

AU - Hormodaly, J.

AU - Barnett, Baruch

PY - 1972/11/15

Y1 - 1972/11/15

N2 - From the optical absorption spectrum of Ce3+ in borate and phosphate glasses, we calculate the nephelauxetic effect in the 4f-5d transition and the crystal field strength in these hosts. Some effects of covalency on the Ce3+-ligand bond are discussed and the bond-forming f-orbitals suggested.

AB - From the optical absorption spectrum of Ce3+ in borate and phosphate glasses, we calculate the nephelauxetic effect in the 4f-5d transition and the crystal field strength in these hosts. Some effects of covalency on the Ce3+-ligand bond are discussed and the bond-forming f-orbitals suggested.

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Ce³⁺ as a probe of the crystal field and the nature of the impurity-ligand bond in borate and phosphate glasses

Abstract

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