Charge fluctuations in Europium in metallic EuCu2Si2

E. R. Bauminger*, D. Froindlich, I. Nowik, S. Ofer, I. Felner, I. Mayer

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

210 Scopus citations

Abstract

Recoilless-absorption measurements of the 21.6-keV γ ray of Eu151 in EuCu2Si2 reveal an absorption line which has a strongly temperature-dependent isomer shift. The lines fall at neither the Eu3+ nor the Eu2+ valence positions, but in between. The results are interpreted in terms of fast fluctuations (τ<3.5×10-11 sec) of an electron between the localized 4f level and the conduction band. The difference in energy between the Eu2+ and the Eu3+ states in EuCu2Si2 is found to be about 0.07 eV.

Original languageEnglish
Pages (from-to)1053-1056
Number of pages4
JournalPhysical Review Letters
Volume30
Issue number21
DOIs
StatePublished - 1973

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