TY - JOUR
T1 - Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris(tertiary phosphine)cobalt compounds
AU - Mohtachemi, R.
AU - Kannert, G.
AU - Schumann, H.
AU - Chocron, S.
AU - Michman, M.
PY - 1986/8/12
Y1 - 1986/8/12
N2 - Complexes of the type L3CoCH3 have been prepared in which L = Ph3P, P2PCH3, PhP(CH3)2, Ph2PGe(CH3)3, Ph2PSn(CH3)3, Ph3As, and R = CH3, Ph, and (CH3)3Si. Decomposition of these complexes under mild conditions in several solvents has been studied. Among the identified products are benzene, toluene, biphenyl, and rearranged phosphines, such as Ph3P from [Ph2PCH3]3CoCH3 or Ph2PCH3 from [Ph2PGe(CH3)3]3CoCH3.
AB - Complexes of the type L3CoCH3 have been prepared in which L = Ph3P, P2PCH3, PhP(CH3)2, Ph2PGe(CH3)3, Ph2PSn(CH3)3, Ph3As, and R = CH3, Ph, and (CH3)3Si. Decomposition of these complexes under mild conditions in several solvents has been studied. Among the identified products are benzene, toluene, biphenyl, and rearranged phosphines, such as Ph3P from [Ph2PCH3]3CoCH3 or Ph2PCH3 from [Ph2PGe(CH3)3]3CoCH3.
UR - http://www.scopus.com/inward/record.url?scp=33845740418&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)99664-5
DO - 10.1016/S0022-328X(00)99664-5
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AN - SCOPUS:33845740418
SN - 0022-328X
VL - 310
SP - 107
EP - 114
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -