Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris(tertiary phosphine)cobalt compounds

R. Mohtachemi; G. Kannert; H. Schumann; S. Chocron; M. Michman

doi:10.1016/S0022-328X(00)99664-5

Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris(tertiary phosphine)cobalt compounds

R. Mohtachemi^*
, G. Kannert
, H. Schumann
, S. Chocron
, M. Michman

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Complexes of the type L₃CoCH₃ have been prepared in which L = Ph₃P, P₂PCH₃, PhP(CH₃)₂, Ph₂PGe(CH₃)₃, Ph₂PSn(CH₃)₃, Ph₃As, and R = CH₃, Ph, and (CH₃)₃Si. Decomposition of these complexes under mild conditions in several solvents has been studied. Among the identified products are benzene, toluene, biphenyl, and rearranged phosphines, such as Ph₃P from [Ph₂PCH₃]₃CoCH₃ or Ph₂PCH₃ from [Ph₂PGe(CH₃)₃]₃CoCH₃.

Original language	English
Pages (from-to)	107-114
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	310
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)99664-5
State	Published - 12 Aug 1986

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title = "Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris(tertiary phosphine)cobalt compounds",

abstract = "Complexes of the type L3CoCH3 have been prepared in which L = Ph3P, P2PCH3, PhP(CH3)2, Ph2PGe(CH3)3, Ph2PSn(CH3)3, Ph3As, and R = CH3, Ph, and (CH3)3Si. Decomposition of these complexes under mild conditions in several solvents has been studied. Among the identified products are benzene, toluene, biphenyl, and rearranged phosphines, such as Ph3P from [Ph2PCH3]3CoCH3 or Ph2PCH3 from [Ph2PGe(CH3)3]3CoCH3.",

author = "R. Mohtachemi and G. Kannert and H. Schumann and S. Chocron and M. Michman",

year = "1986",

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T1 - Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris(tertiary phosphine)cobalt compounds

AU - Mohtachemi, R.

AU - Kannert, G.

AU - Schumann, H.

AU - Chocron, S.

AU - Michman, M.

PY - 1986/8/12

Y1 - 1986/8/12

N2 - Complexes of the type L3CoCH3 have been prepared in which L = Ph3P, P2PCH3, PhP(CH3)2, Ph2PGe(CH3)3, Ph2PSn(CH3)3, Ph3As, and R = CH3, Ph, and (CH3)3Si. Decomposition of these complexes under mild conditions in several solvents has been studied. Among the identified products are benzene, toluene, biphenyl, and rearranged phosphines, such as Ph3P from [Ph2PCH3]3CoCH3 or Ph2PCH3 from [Ph2PGe(CH3)3]3CoCH3.

AB - Complexes of the type L3CoCH3 have been prepared in which L = Ph3P, P2PCH3, PhP(CH3)2, Ph2PGe(CH3)3, Ph2PSn(CH3)3, Ph3As, and R = CH3, Ph, and (CH3)3Si. Decomposition of these complexes under mild conditions in several solvents has been studied. Among the identified products are benzene, toluene, biphenyl, and rearranged phosphines, such as Ph3P from [Ph2PCH3]3CoCH3 or Ph2PCH3 from [Ph2PGe(CH3)3]3CoCH3.

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AN - SCOPUS:33845740418

SN - 0022-328X

VL - 310

SP - 107

EP - 114

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris(tertiary phosphine)cobalt compounds

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