Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Marc Moselage, Nicolas Sauermann, Julian Koeller, Weiping Liu, Dmitri Gelman, Lutz Ackermann*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

94 Scopus citations

Abstract

Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

Original languageAmerican English
Article numberst-2015-b0163-l
Pages (from-to)1596-1600
Number of pages5
JournalSynlett
Volume26
Issue number11
DOIs
StatePublished - 1 Jul 2015

Bibliographical note

Publisher Copyright:
© Georg Thieme Verlag Stuttgart, New York Synlett 2015.

Keywords

  • C-H activation
  • C-O cleavage
  • allylation
  • cobalt
  • heteroarene

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