Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Marc Moselage; Nicolas Sauermann; Julian Koeller; Weiping Liu; Dmitri Gelman; Lutz Ackermann

doi:10.1055/s-0034-1379927

Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Marc Moselage, Nicolas Sauermann, Julian Koeller, Weiping Liu, Dmitri Gelman, Lutz Ackermann^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

Original language	English
Article number	st-2015-b0163-l
Pages (from-to)	1596-1600
Number of pages	5
Journal	Synlett
Volume	26
Issue number	11
DOIs	https://doi.org/10.1055/s-0034-1379927
State	Published - 1 Jul 2015

Bibliographical note

Publisher Copyright:
© Georg Thieme Verlag Stuttgart, New York Synlett 2015.

Keywords

C-H activation
C-O cleavage
allylation
cobalt
heteroarene

Access to Document

10.1055/s-0034-1379927

Cite this

@article{ead885cc20b24c9a87a6241b7afcea3b,

title = "Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage",

abstract = "Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.",

keywords = "C-H activation, C-O cleavage, allylation, cobalt, heteroarene",

author = "Marc Moselage and Nicolas Sauermann and Julian Koeller and Weiping Liu and Dmitri Gelman and Lutz Ackermann",

note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart, New York Synlett 2015.",

year = "2015",

month = jul,

day = "1",

doi = "10.1055/s-0034-1379927",

language = "אנגלית",

volume = "26",

pages = "1596--1600",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "11",

}

TY - JOUR

T1 - Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

AU - Moselage, Marc

AU - Sauermann, Nicolas

AU - Koeller, Julian

AU - Liu, Weiping

AU - Gelman, Dmitri

AU - Ackermann, Lutz

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart, New York Synlett 2015.

PY - 2015/7/1

Y1 - 2015/7/1

N2 - Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

AB - Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

KW - C-H activation

KW - C-O cleavage

KW - allylation

KW - cobalt

KW - heteroarene

UR - http://www.scopus.com/inward/record.url?scp=84931955088&partnerID=8YFLogxK

U2 - 10.1055/s-0034-1379927

DO - 10.1055/s-0034-1379927

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:84931955088

SN - 0936-5214

VL - 26

SP - 1596

EP - 1600

JO - Synlett

JF - Synlett

IS - 11

M1 - st-2015-b0163-l

ER -

Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this