Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Marc Moselage; Nicolas Sauermann; Julian Koeller; Weiping Liu; Dmitri Gelman; Lutz Ackermann

doi:10.1055/s-0034-1379927

Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Marc Moselage
, Nicolas Sauermann
, Julian Koeller
, Weiping Liu
, Dmitri Gelman
, Lutz Ackermann^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

Original language	English
Article number	st-2015-b0163-l
Pages (from-to)	1596-1600
Number of pages	5
Journal	Synlett
Volume	26
Issue number	11
DOIs	https://doi.org/10.1055/s-0034-1379927
State	Published - 1 Jul 2015

Bibliographical note

Publisher Copyright:
© Georg Thieme Verlag Stuttgart, New York Synlett 2015.

Keywords

C-H activation
C-O cleavage
allylation
cobalt
heteroarene

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10.1055/s-0034-1379927

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title = "Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage",

abstract = "Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.",

keywords = "C-H activation, C-O cleavage, allylation, cobalt, heteroarene",

author = "Marc Moselage and Nicolas Sauermann and Julian Koeller and Weiping Liu and Dmitri Gelman and Lutz Ackermann",

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T1 - Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

AU - Moselage, Marc

AU - Sauermann, Nicolas

AU - Koeller, Julian

AU - Liu, Weiping

AU - Gelman, Dmitri

AU - Ackermann, Lutz

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart, New York Synlett 2015.

PY - 2015/7/1

Y1 - 2015/7/1

N2 - Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

AB - Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

KW - C-H activation

KW - C-O cleavage

KW - allylation

KW - cobalt

KW - heteroarene

UR - https://www.scopus.com/pages/publications/84931955088

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DO - 10.1055/s-0034-1379927

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SN - 0936-5214

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JO - Synlett

JF - Synlett

IS - 11

M1 - st-2015-b0163-l

ER -

Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

Abstract

Bibliographical note

Keywords

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