Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride

Itamar Willner*, Jacqueline Rosengaus, Silvio Biali

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

2,6-Bis(aminocyclohexyl)-4-methoxy triazine (1) and 2,4,6-tris(aminocyclohexyl) triazine (2) act as molecular hosts for bemegride (3) by complementary H-bonded interactions. 1H-NMR and 13C-NMR spectra reveal that association of (3) proceeds through discrimination of selected conformations of the host molecules. The association constants of (3) to (1) and (2) are K=449 M-1 and K=915 M-1, respectively.

Original languageAmerican English
Pages (from-to)3805-3808
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number26
DOIs
StatePublished - 23 Jun 1992

Fingerprint

Dive into the research topics of 'Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride'. Together they form a unique fingerprint.

Cite this