Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride

Itamar Willner; Jacqueline Rosengaus; Silvio Biali

doi:10.1016/0040-4039(92)80030-N

Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride

Itamar Willner^*
, Jacqueline Rosengaus
, Silvio Biali

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

2,6-Bis(aminocyclohexyl)-4-methoxy triazine (1) and 2,4,6-tris(aminocyclohexyl) triazine (2) act as molecular hosts for bemegride (3) by complementary H-bonded interactions. ¹H-NMR and ¹³C-NMR spectra reveal that association of (3) proceeds through discrimination of selected conformations of the host molecules. The association constants of (3) to (1) and (2) are K=449 M^-1 and K=915 M^-1, respectively.

Original language	English
Pages (from-to)	3805-3808
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	26
DOIs	https://doi.org/10.1016/0040-4039(92)80030-N
State	Published - 23 Jun 1992

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title = "Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride",

abstract = "2,6-Bis(aminocyclohexyl)-4-methoxy triazine (1) and 2,4,6-tris(aminocyclohexyl) triazine (2) act as molecular hosts for bemegride (3) by complementary H-bonded interactions. 1H-NMR and 13C-NMR spectra reveal that association of (3) proceeds through discrimination of selected conformations of the host molecules. The association constants of (3) to (1) and (2) are K=449 M-1 and K=915 M-1, respectively.",

author = "Itamar Willner and Jacqueline Rosengaus and Silvio Biali",

year = "1992",

month = jun,

day = "23",

doi = "10.1016/0040-4039(92)80030-N",

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journal = "Tetrahedron Letters",

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T1 - Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride

AU - Willner, Itamar

AU - Rosengaus, Jacqueline

AU - Biali, Silvio

PY - 1992/6/23

Y1 - 1992/6/23

N2 - 2,6-Bis(aminocyclohexyl)-4-methoxy triazine (1) and 2,4,6-tris(aminocyclohexyl) triazine (2) act as molecular hosts for bemegride (3) by complementary H-bonded interactions. 1H-NMR and 13C-NMR spectra reveal that association of (3) proceeds through discrimination of selected conformations of the host molecules. The association constants of (3) to (1) and (2) are K=449 M-1 and K=915 M-1, respectively.

AB - 2,6-Bis(aminocyclohexyl)-4-methoxy triazine (1) and 2,4,6-tris(aminocyclohexyl) triazine (2) act as molecular hosts for bemegride (3) by complementary H-bonded interactions. 1H-NMR and 13C-NMR spectra reveal that association of (3) proceeds through discrimination of selected conformations of the host molecules. The association constants of (3) to (1) and (2) are K=449 M-1 and K=915 M-1, respectively.

UR - https://www.scopus.com/pages/publications/0026663992

U2 - 10.1016/0040-4039(92)80030-N

DO - 10.1016/0040-4039(92)80030-N

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AN - SCOPUS:0026663992

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 26

ER -

Conformational selectivity in the formation of H-bonded assemblies between Di- and triamino triazines and bemegride

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