Conformationally restricted calix[8]arenes substituted at all methylene bridges

Katerina Kogan, Silvio E. Biali*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Reaction under SN1 conditions of the octabromocalix[8]arene derivative 2d with alcohols proceeds in nonstereoselective fashion, but all-cis octaryl derivatives are the single major products in the reaction with arenes. The incorporation of aryl substituents at the bridges rigidifies the calix[8]arene skeleton.

Original languageAmerican English
Pages (from-to)7240-7244
Number of pages5
JournalJournal of Organic Chemistry
Volume76
Issue number17
DOIs
StatePublished - 2 Sep 2011

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