Conformationally restricted calix[8]arenes substituted at all methylene bridges

Katerina Kogan; Silvio E. Biali

doi:10.1021/jo2009643

Conformationally restricted calix[8]arenes substituted at all methylene bridges

Katerina Kogan
, Silvio E. Biali^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Reaction under S_N1 conditions of the octabromocalix[8]arene derivative 2d with alcohols proceeds in nonstereoselective fashion, but all-cis octaryl derivatives are the single major products in the reaction with arenes. The incorporation of aryl substituents at the bridges rigidifies the calix[8]arene skeleton.

Original language	English
Pages (from-to)	7240-7244
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	76
Issue number	17
DOIs	https://doi.org/10.1021/jo2009643
State	Published - 2 Sep 2011

Access to Document

10.1021/jo2009643

Cite this

@article{d0a8719eb3f34612bb1342623ea1c5b6,

title = "Conformationally restricted calix[8]arenes substituted at all methylene bridges",

abstract = "Reaction under SN1 conditions of the octabromocalix[8]arene derivative 2d with alcohols proceeds in nonstereoselective fashion, but all-cis octaryl derivatives are the single major products in the reaction with arenes. The incorporation of aryl substituents at the bridges rigidifies the calix[8]arene skeleton.",

author = "Katerina Kogan and Biali, \{Silvio E.\}",

year = "2011",

month = sep,

day = "2",

doi = "10.1021/jo2009643",

language = "אנגלית",

volume = "76",

pages = "7240--7244",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Conformationally restricted calix[8]arenes substituted at all methylene bridges

AU - Kogan, Katerina

AU - Biali, Silvio E.

PY - 2011/9/2

Y1 - 2011/9/2

N2 - Reaction under SN1 conditions of the octabromocalix[8]arene derivative 2d with alcohols proceeds in nonstereoselective fashion, but all-cis octaryl derivatives are the single major products in the reaction with arenes. The incorporation of aryl substituents at the bridges rigidifies the calix[8]arene skeleton.

AB - Reaction under SN1 conditions of the octabromocalix[8]arene derivative 2d with alcohols proceeds in nonstereoselective fashion, but all-cis octaryl derivatives are the single major products in the reaction with arenes. The incorporation of aryl substituents at the bridges rigidifies the calix[8]arene skeleton.

UR - https://www.scopus.com/pages/publications/80052150420

U2 - 10.1021/jo2009643

DO - 10.1021/jo2009643

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:80052150420

SN - 0022-3263

VL - 76

SP - 7240

EP - 7244

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 17

ER -

Conformationally restricted calix[8]arenes substituted at all methylene bridges

Abstract

Access to Document

Other files and links

Fingerprint

Cite this