Abstract
It is pointed out that the interaction between degenerate configurations produces a modification in zero order of the expectation values for atomic systems. For certain operators, the modification will be large, an example being the operator appropriate to the calculation of the mass polarization correction.
Original language | English |
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Pages (from-to) | 378-380 |
Number of pages | 3 |
Journal | Journal of Molecular Spectroscopy |
Volume | 10 |
Issue number | 1-6 |
DOIs | |
State | Published - 1963 |
Externally published | Yes |