Coupled dissolution-precipitation reactions as a potential method for mitigating contaminant transport in carbonate aquifers

Anat Cohen, Roni Grayevsky, Yoni Israeli, Simon Emmanuel*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations


Subsurface barriers are often used to mitigate the spread of contaminants in groundwater. Current methods typically involve the injection of slurries into aquifers, a process that clogs porosity and reduces hydraulic conductivity. An alternative way to achieve this effect in calcareous aquifers could be to inject a fluid that dissolves the existing carbonate minerals and induces the formation of phases that have higher molar volumes. While such mineral replacement reactions are known to affect hydraulic conductivity, their ability to impede contaminant transport has not been tested. In this study, we injected oxalic acid into a pseudo-2D flow through cell containing calcitic sand, which simulated a calcareous aquifer. The oxalic acid causes the dissolution of calcite, as well as the precipitation of calcium oxalate minerals, in a reaction zone that spreads out from the point of injection. We found that this process reduces the water discharge in the cell by up to 80%, and caused the flow velocity around the reaction zone to drop from 20 cm h−1 to <0.1 cm h−1. Mineralogical analyses and electron microscopy indicate that permeability is reduced primarily by partitioning of the intergranular voids by micrometer sized calcium oxalate crystals. Our results suggest that coupled dissolution-precipitation reactions could be a feasible method for deploying subsurface barriers in aquifers.

Original languageAmerican English
Article number104052
JournalAdvances in Water Resources
StatePublished - Nov 2021

Bibliographical note

Funding Information:
The Israel Ministry of Energy and the Israel Water Authority are thanked for their generous financial support.

Publisher Copyright:
© 2021


  • Calcite
  • Calcium oxalate
  • Groundwater
  • Porosity
  • Porous media


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