Covalent radii from ionization energies of isoelectronic series

Noam Agmon

doi:10.1016/j.cplett.2014.01.037

Covalent radii from ionization energies of isoelectronic series

Noam Agmon^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Slater's covalent radii agree nicely with experiment when the effective principal quantum number and the screening constant for the outermost electron are taken from fits of the hydrogen-like energy level expression to ionization energies in isoelectronic series. This establishes a simple connection between the two prominent periodic properties of atoms, namely, their radius and (effective) ionization energy.

Original language	English
Pages (from-to)	214-219
Number of pages	6
Journal	Chemical Physics Letters
Volume	595-596
DOIs	https://doi.org/10.1016/j.cplett.2014.01.037
State	Published - 18 Mar 2014

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abstract = "Slater's covalent radii agree nicely with experiment when the effective principal quantum number and the screening constant for the outermost electron are taken from fits of the hydrogen-like energy level expression to ionization energies in isoelectronic series. This establishes a simple connection between the two prominent periodic properties of atoms, namely, their radius and (effective) ionization energy.",

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AB - Slater's covalent radii agree nicely with experiment when the effective principal quantum number and the screening constant for the outermost electron are taken from fits of the hydrogen-like energy level expression to ionization energies in isoelectronic series. This establishes a simple connection between the two prominent periodic properties of atoms, namely, their radius and (effective) ionization energy.

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Covalent radii from ionization energies of isoelectronic series

Abstract

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